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991.
Osman Canko Ferhat Taşkın Murat Atiş Nazmiye Kervan Selçuk Kervan 《Journal of Superconductivity and Novel Magnetism》2016,29(10):2573-2578
The electronic structure and magnetic properties of the Fe2ZrP full-Heusler compound has been investigated by using ab initio calculations with the full-potential linearized augmented plane wave (FLAPW) method. The exchange-correlation functionals are taken into account within the generalized gradient approximation (GGA). Energetically, the AlCu2Mn-type structure of the full-Heusler Fe2ZrP is energetically more preferable than that of the CuHg2Ti-type structure and it exhibits half-metallic ferrimagnet. The calculated total spin moment is found as 1 μ B at the equilibrium lattice constant a 0=5.90Å which remarkably agrees with the Slater-Pauling rule of M t = Z t ?24. While the spin-up band is metallic, the spin-down band has a semiconductor behavior with a gap of 0.593 eV and the spin-flip gap is 0.129 eV. The negative formation energy is shown as an evidence of the thermodynamic stability of alloy. The dependencies of the magnetic and electronic properties on the lattice constant are also discussed. The estimated Curie temperature is 752 K in the mean field approximation. 相似文献
992.
Murat Tiryakioğlu 《Materials Science & Technology》2019,35(7):872-874
The adequacy of the model originally developed by Charbon and Rappaz for nucleation temperatures of grains to the formation of hydrogen pores during the solidification of aluminium alloys has been investigated. By using four datasets from the literature, it has been found that the Gaussian distribution assumed in the original model for nucleation temperature has provided poor fits to all datasets with systematic error. The hypothesis that undercooling follows the lognormal distribution has been tested. In all four cases, the hypotheses that undercooling is lognormal could not be rejected. 相似文献
993.
Molecular dynamics (MD) method is used to simulate shear driven argon gas flows in the early transition and free molecular flow regimes to investigate surface effects as a function of the surface–gas potential strength ratio (εwf/εff). Results show a bulk flow region and a near wall region that extends three molecular diameters away from the surfaces. Within the near wall region the velocity, density, and shear stress distributions exhibit deviations from the kinetic theory predictions. Increased εwf/εff results in increased gas density, leading toward monolayer adsorption on surfaces. The near wall velocity profile shows reduced gas slip, and eventually velocity stick with increased εwf/εff. Using MD predicted shear stress values and kinetic theory, tangential momentum accommodation coefficients (TMAC) are calculated as a function of εwf/εff, and TMAC values are shown to be independent of the Knudsen number. Presence of this near wall region breaks down the dynamic similarity between rarefied and nanoscale gas flows. 相似文献
994.
In this study, the effect of crosslinking conditions was investigated to obtain insoluble poly(ethylene oxide) (PEO) nanofiber mats having an ultraviolet (UV) initiating and crosslinking agent, pentaerythritol triacrylate (PETA), with various ratios in the presence or absence of UV irradiation at 366 nm. At first, PEO nanofibers were electrospun from 400,000 and 600,000 g/mole molecular weights of PEO and they were compared in terms of diameter and fiber morphology. Whereas applied voltage in the range of 10–25 kV had no significant effect on the fiber morphology, fiber diameters varied by voltage. An increase in the flow rate from 0.25 to 1.00 mL h?1 had an effect in favor of fabricating thicker fibers. The effect of distance to collector on the diameter and morphology was not distinctive. Fibers having irregular morphology and beads appeared with increasing the polymer concentration from 4 to 8 % w/v. Prior crosslinking, electrospinning process at selected conditions was applied to the PEO (600,000) including PETA and PEO-PETA nanofibers were obtained. Besides PETA concentration and UV application, drying conditions before UV irradiation were also found effective to obtain stable fibers in aqueous media. PEO nanofibers electrospun in the presence of 10 % PETA (w/w), dried for 8 days at 37 °C in an air atmosphere and then, irradiated with UV for 50 min were found most stable in aqueous media. However, crosslinking was also achieved in the absence of UV. 相似文献
995.
Neodymium-substituted CuFeO2 samples were investigated according to their crystal and electronic properties via the general formula Nd x Cu1?x FeO2. The crystal structure analysis results revealed polycrystalline formations in the sample and a change in crystalline sizes with the substituted heavy fermion “Nd.” Increasing the Nd amount in the sample was determined to cause a disturbance on the Cu-Fe planes that supports the formation of crystal structures with low crystal symmetries such as monoclinic or triclinic geometries. To obtain the background mechanisms of the crystal properties, the X-ray absorption fine structure spectroscopy technique was used to study the electronic properties of the samples. Prominent changes in the crystal structures due to 4f electrons’ contributions from the substituted Nd atoms as the main “role player” in the phase transitions were determined. The Nd atoms were observed as the key element guiding the entire phenomenon as a result of their large size and narrow 4f levels. Also, magnetic properties of the samples were tested at room temperature and without an applied magnetic field by X-ray magnetic circular dichroism study due to previous studies that reported the parent oxide CuFeO2 to have magnetic ordering at T N = 11 K (?262 °C). Except the sample for x = 1.0 (NdFeO3), no magnetic ordering was observed at room temperature; i.e., all of the samples showed paramagnetic behaviors. 相似文献
996.
Selçuk Bilgen İkbal Sarıkaya Lokman Murat Ayyıldız 《Energy Sources, Part A: Recovery, Utilization, and Environmental Effects》2016,38(20):3055-3064
The correlation proposed in this work has been compared statistically with a larger database of bio-oils taken from values in the literature. The correlation developed here uses only one formula used in the major constituents of elementary analyses. Seventy-nine data points have been used to derive this correlation. This correlation is valid for bio-oils having a broad range of elemental composition, that is C: 8.2–89.3%; H: 4.6–14.4%; O: 1.4–76.9%; N: 0.0–10.8%; and S: 0.0–1.8%. It presents an average absolute error of 1.21% and bias error of 0.59%, and thereby establishes its versatility. 相似文献
997.
The majority of abandoned limestone powder wastes (LPW) and wood sawdust wastes (WSW) is accumulated from the countries all over the world and causes certain serious environmental problems and health hazards. This paper presents a parametric experimental study which investigates the potential use of WSW–LPW combination for producing a low-cost and lightweight composite as a building material. Some of the physical and mechanical properties of concrete mixes having high level of WSW and LPW are investigated. The obtained compressive strength, flexural strength, unit weight, ultrasonic pulse velocity (UPV) and water absorption values satisfy the relevant international standards. The results show that the effect of high-level replacement of WSW with LPW does not exhibit a sudden brittle fracture even beyond the failure loads, indicates high energy absorption capacity, reduces the unit weight dramatically and introduces smother surface compared to the current concrete bricks in the market. It shows a potential to be used for walls, wooden board substitute, economically alternative to the concrete blocks, ceiling panels, sound barrier panels, etc. 相似文献
998.
AbstractHousing prices have increased substantially in some emerging markets in recent years. Turkish housing market has also experienced a boom over the last decade with rapid house price appreciations. This study is the first to employ two different house price indexes to analyze housing bubble in Turkey in two different time periods, 2010:M1–2014:M12 and 2007:M6–2014:M12. We first capture the determinants of housing price by employing Bounds test and then examine whether rising house prices have been justified by fundamentals by employing OLS/FMOLS/DOLS, Kalman filter and ARIMA models. The Bounds test results suggest that there is a long-term cointegration among house price indexes and housing rent, construction cost and real mortgage interest rate. The results imply that the Turkish housing market has experienced some cases of overvaluation, but not bubble formation. This evidence has several implications for house price dynamics and risks in the Turkish housing market. Based on Turkish experience, the study also draws policy implications for emerging housing markets. 相似文献
999.
Özgür Kalelioğlu Kemal Zorlu Mehmet Ali· Kurt Murat Gül 《International journal of remote sensing》2013,34(11):2997-3011
In the Uluk??la basin (Central Anatolia, Turkey) several geological mapping campaigns were carried out using conventional field methods to delineate compositionally different Middle–Upper Eocene dykes. However, complete and correct mapping of these dykes was hampered by rugged terrain, lack of road access, wide spatial dyke distributions with small exposures and diverse weathering of these dykes. For these reasons, Landsat‐5 Thematic Mapper (TM) satellite image of the study area was used to facilitate delineation of the exact boundaries of gabbroic, dioritic and trachytic dykes found in the area. Remotely sensed data were analysed using several image enhancement procedures, including colour composites, band ratios, principal components analysis (PCA), and Crosta technique. Results obtained from all the processes were examined, and it was found that dyke boundaries are best visible in the PCA123 image; RGB 731 colour composite; TM band ratio 5/7, 5/1, 4 combination; and 1457‐PC4 image obtained by Crosta technique. The alteration differences of three dyke groups are enhanced much better in the 1457‐PC4 image obtained by Crosta technique, which highlights the hydroxyl‐bearing minerals as white‐coloured pixels. Using computer‐enhanced multi‐spectral remote sensing data, we were able to map the boundaries and spatial distributions of compositionally different dykes, which otherwise is an overwhelmingly difficult task to achieve using conventional field methods. In similar settings, remote sensing techniques applied in this study may provide an efficient and low‐cost alternative to time‐consuming and physically demanding field‐mapping campaigns. 相似文献
1000.
We develop an efficient allocation-based solution framework for a class of two-facility location–allocation problems with dense demand data. By formulating the problem as a multi-dimensional boundary value problem, we show that previous results for the discrete demand case can be extended to problems with highly dense demand data. Further, this approach can be generalized to non-convex allocation decisions. This formulation is illustrated for the Euclidean metric case by representing the affine bisector with two points. A specialized multi-dimensional shooting algorithm is presented and illustrated on an example. Comparisons with two alternative methods through a computational study confirm the efficiency of the proposed methodology. 相似文献